Product ID:70203 MORPHOLINE
MSDS Date:12/02/1992
FSC:6810
NIIN:00-616-9437
MSDS Number: BFJCV

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 713-650-4000

Cage: 38431

Telephone: 713-953-4260

Cage: 3B431

MORPHOLINE

CAS: 110-91-8

RTECS: QD6475000

Fraction By Weight: 91.0%

OSHA PEL S,20 PPM/30 STEL

ACGIH TLV: S, 20 PPM; 9293

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 1050 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION AND CHEMICAL BURNS OF
THE EYES THAT MAY RESULT IN SEVERE EYE DAMAGE AND BLINDNESS. SKIN:
SEVERE IRRITATION, CHEMICAL BURNS, AND POSSIBLE TISSUE DESTRUCTION.
INHALATION: VAPORS OR MIST S CAUSE IRRITATION OF
NOSE,THROAT,RESPIRATORY TRACT, AND LUNG DAMAGE. INGESTION: BURNS OF
THE MOUTH,THROAT,AND STOMACH.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:EYES: IRRITATION, PAIN, AND TEARING. SKIN:
IRRITATION, PAIN, AND BLISTER FORMATION. INHALATION: IRRITATION OF
NOSE, THROAT, AND LUNGS. DIFFICULT BREATHING, HEADACHE, NAUSEA, AND
VOMITING. INGESTION: B URNING OF MOUTH, THROAT, AND STOMACH WITH
ABDOMINAL AND CHEST PAIN, NAUSEA, VOMITING, DIARRHEA, THIRST, AND
WEAKNESS.
Medical Cond Aggravated by Exposure:VAPOR, DUST OR MIST MAY AGGRIVATE
EXISTING RESPIRATORY CONDITIONS, SUCH AS ASTHMA, BRONCHITIS, AND
INFLAMMATORY OR FIBROTIC RESPIRATORY DISEASE. SKIN CONTACT MAY
AGGRIVATE EXISTING DERMATITIS.

First Aid:EYES: FLUSH WITH LARGE AMOUNT OF WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH AREA WITH
LARGE AMOUNT OF WATER. GET MEDICAL ATTENTION. INHALATION: REMOVE TO
FRESH AIR. IF NOT BREATHING GIVE CPR. IF BREATHING DIFFICULT GIVE
OXYGEN. GET MEDICAL ATTENTION. INGESTION: GIVE PATIENT TWO GLASSES
OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:95.0F,35.0C
Autoignition Temp:Autoignition Temp Text:590F
Lower Limits:1.8
Upper Limits:10.8
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER
MAY BE INEFFECTIVE ON FLAMES, BUT USED TO COOL FIRE-EXPOSED
CONTAINERS.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:PRODUCT VAPORS MAY TRAVEL A CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY
EXPLODE IN A FIRE.

Spill Release Procedures:VENTILATE AREA. ELIMINATE ALL IGNITION
SOURCES. USE SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED AIR
MASK. CONTAIN SPILL IF POSSIBLE. USE SUITABLE INERT ABSORBENT
MATERIAL AND RECOVER FOR PROPER DIS POSAL. PREVENT ENTRY INTO
SEWERS AND WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY WELL VENTILATED
AREA. KEEP AWAY FROM HEAT, FLAMES, SPARKS AND IGNITION SOURCES. USE
SPARK-PROOF TOOLS. DO NOT BREATHE VAPORS.
Other Precautions:GROUND AND BOND SHIPPING CONTAINER, TRANSFER LINE,
AND RECEIVING CONTAINER. MATERIAL MAY BE AT ELEVATED TEMPERATURES
AND/OR PRESSURES. EXERCISE CARE WHEN OPENING BLEEDERS AND SAMPLING
PORTS. AVOID CON TACT WITH EYES AND SKIN.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
VAPORS/MIST IF ABOVE PEL/TLV OR SCBA IN AND ENCLOSED AREA.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL TYPE GOGGLES WITH FACE SHIELD.
Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS,
COVERALLS OR LAB COAT MUST BE WORN. DO NOT WEAR CONTACT LENSES.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
HAVE EYE WASH STATION AND SAFETY SHOWER AVAILABLE. MISUSE OF EMPTY
CONTAINERS CAN BE HAZARDOUS. CUTTING OR WELDING OF EMPTY CONTAINERS
MIGHT CAUSE FIRE, EXPLOSION, OR TOXIC FUMES FROM RESIDUES. DO NOT
PRESSURIZE OR EXPOSE TO OPEN FLAME OR HEAT. KEEP CONTAINER CLOSED
AND BUNGS IN PLACE. AVOID CONTACT WITH EYES AND SKIN.

HCC:F3
Boiling Pt:B.P. Text:263F,128C
Vapor Pres:7 MM HG
Vapor Density:3.0,AIR=1
Spec Gravity:1.0017(WATER=1)
pH:11.2
Viscosity:2.23 CP @20C
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, AMMONIA ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS. DO NOT ADD WITH NITRITES OR NITROSATING
AGENTS,(MAY FORM NITROSAMINES A POTENTIAL CARCINOGEN).
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES,
AND ALL SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN, AMMONIA, ALDEHYDES, AND KEYTONES.

Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.